Sodium hydroxide

Sodium hydroxide

CAS No.: 1310-73-2
Molecular Formula: NaOH
Molecular weight: 39.99711
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product description
Sodium hydroxide, also known as caustic soda and caustic soda, has the chemical formula NaOH. It is a highly corrosive strong base, usually in white flakes or granules. It can be mixed with water to form an alkaline solution, and can also be dissolved in methanol and ethanol. This alkaline substance is deliquescent and will absorb water vapor in the air, as well as acidic gases such as carbon dioxide. Sodium hydroxide is one of the commonly used chemicals. It has a wide range of applications and is a necessity in many industrial processes: it is often used in the manufacture of wood pulp paper, textiles, soaps and other detergents, and is also used in household alkaline drain cleaning products.


Chemical Properties

PropertyValue
Melting point

681 °C(lit.)

Boiling point

1390°C

Density

1.515 g/mL at 20 °C

Vapor Density

<1 (vs air)

Vapor Pressure

1 mm Hg ( 745 °C)

Refractive index

1,473-1,475

Fp

176-178°C

Storage temp.

Room temp

Solubility

H2O: 1 M at 20 °C, clear, colorless

Form

Beads

Color

White

Specific Gravity

2.13

Odor

Odorless

PH Range

13 - 14

PH

10.98(1 mM solution);11.95(10 mM solution);12.88(100 mM solution);

Water Solubility

SOLUBLE

Sensitive

Air Sensitive & Hygroscopic

Decomposition

176-178 ºC

λmax

λ: 260 nm Amax: 0.015λ: 280 nm Amax: 0.01

Merck

14,8627

Dielectric constant

57.5(25℃)

Exposure limits

TLV-TWA air 2 mg/m3 (OSHA); ceiling 2 mg/m3 (ACGIH) and 2 mg/m3/15 min (NIOSH).

Stability:

Hygroscopic

CAS DataBase Reference

1310-73-2(CAS DataBase Reference)

NIST Chemistry Reference

Sodium hydroxide(1310-73-2)

EPA Substance Registry System

Sodium hydroxide (1310-73-2)


Safety Information

PropertyValue

Hazard Codes

C,Xi

Risk Statements

36/38-35-34

Safety Statements

26-45-37/39-24/25-36/37/39

RIDADR

UN 1824 8/PG 2

WGK Germany

1

RTECS

TT2975000

F

8

TSCA

Yes

HS Code

2815 11 00

HazardClass

8

PackingGroup

II

Hazardous Substances Data

1310-73-2(Hazardous Substances Data)

Toxicity

LD orally in rabbits: 500 mg/kg (10% soln) (Fazekas)

IDLA

10 mg/m3


Product Usage

Sodium hydroxide has a broad range of applications. In chemical experiments, it serves not only as a reagent but also as an alkaline desiccant due to its strong hygroscopic properties. Caustic soda plays a vital role in the national economy, with numerous industrial sectors relying on it. The largest consumer is the chemical manufacturing industry, followed by paper production, aluminum and tungsten smelting, viscose fiber manufacturing, and soap production. It is also used in the manufacture of dyes, plastics, pharmaceuticals, organic intermediates, reclaimed rubber, metal sodium electrolysis, water treatment, and inorganic salt production such as borax, chromium salts, manganates, and phosphates.


Industrial sodium hydroxide must meet the requirements of national standard GB209-2006;

Industrial ion-exchange membrane sodium hydroxide should comply with GB/T11199-89;

Sodium hydroxide for chemical fiber should meet GB11212-89;

Food-grade sodium hydroxide must conform to GB5175-85.


In industrial contexts, sodium hydroxide is commonly referred to as caustic soda, a name derived from its ability to cause severe skin burns upon contact with concentrated solutions. It dissolves proteins, making alkali burns slower to heal than acid burns. A 0.02% solution instilled into rabbit eyes can damage the corneal epithelium. Toxicity data include: mouse intraperitoneal LD50 of 40 mg/kg and rabbit oral LDLo of 500 mg/kg. Dust can irritate the eyes and respiratory tract, corrode the nasal septum, and damage skin—especially mucous membranes—producing soft scabs that may penetrate deeply and leave permanent scars.

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